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4. Mechanisms and causes
- Mechanical overload and fatigue: cyclic stress, stress concentration points.
- Environmental stress cracking: combined mechanical stress and environmental chemical exposure (solvents, alkalis, acids).
- Hydrolytic degradation: chain scission under moisture and elevated temperature.
- Oxidative degradation: radical‑mediated aging, UV‑induced photodegradation.
- Thermal degradation and thermally induced embrittlement.
- Biological degradation: enzymatic or microbial attack causing localized weakening.
- Processing defects: spinneret defects, uneven coagulation, residual stresses from stretching/drawing, thermal gradients.
- Surface treatments and finishes that promote or inhibit crack initiation.